Google describes technical issues as errors that can prevent it from crawling, indexing or serving your pages. Crawling is Google fetching a page; indexing is Google storing it so it can appear in results. Its examples are server availability, robots.txt fetching and "page not found" errors.
Faults can be site-wide, as when your website is down, or limited to some pages, as with a misplaced noindex tag (an instruction telling Google not to keep a page in results). This guide shows how to check with free tools.